IUPAC Rules for Cycloalkane Nomenclature

  1. For a monosubstituted cycloalkane the ring supplies the root name (table above) and the substituent group is named as usual. A location number is unnecessary.
  2. If the alkyl substituent is large and/or complex, the ring may be named as a substituent group on an alkane.
  3. If two different substituents are present on the ring, they are listed in alphabetical order, and the first cited substituent is assigned to carbon #1. The numbering of ring carbons then continues in a direction (clockwise or counter-clockwise) that affords the second substituent the lower possible location number.
  4. If several substituents are present on the ring, they are listed in alphabetical order. Location numbers are assigned to the substituents so that one of them is at carbon #1 and the other locations have the lowest possible numbers, counting in either a clockwise or counter-clockwise direction.
  5. The name is assembled, listing groups in alphabetical order and giving each group (if there are two or more) a location number.
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