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position of the atom changes relative to the original bond axis

Bending (deformation)

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222- Flashcard

generally require less energy and take place at longer wavelength than the corresponding stretching vibrations

Bending vibrations

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Provides infrared radiation across a range of frequencies.

IR Source

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A reference beam that bypasses the sample, used for baseline correction and normalization.

Reference:

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Selects specific wavelengths of infrared light for analysis.

Monochromator:

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Where the sample is placed for analysis.

Sample Compartment

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Divides the infrared beam into the sample and reference beams

Splitter:

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Measures the intensity of infrared light transmitted through or reflected by the sample.

Detector

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Displays the spectral data obtained from the detector

Readout:

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THREE COMMON TYPES OF INFRARED SPECTROSCOPY

  1. Dispersive Infrared Spectroscopy (DS)
  2. Fourier Transform Instruments (FTIR)
  3. Near Infrared Spectroscopy (NIR)
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“Grating or scanning spectrometers”

Dispersive Infrared Spectroscopy (DS)

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Which use a monochromator to select each wavenumber in turn in order to monitor its intensity after the radiation has passed through the sample

Dispersive Infrared Spectroscopy (DS)

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Key components are the

source, entrance slit, grating (monochromator) and detector.

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