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Cyclohexene, benzene, toluene odor
Gas-like, Gas-like, Rugby-like
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- A class of compounds where a halogen atom or atoms are bound to an sp3 orbital of an alkyl group.
Alkyl halides
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CHCl3
- Chloroform: Organic Solvent)
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CF2Cl2
- Freon-12: Refrigerant CFC)
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- Halothane: anesthetic)
CF3CHClBr
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- alkyl group attached to one carbon. E.g. n-butylchloride
Primary
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- alkyl group attached to two carbon. E.g. sec-butylchloride
Secondary
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- alkyl group attached to three carbon. E.g tert-butyl chloride
Tertiary
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To know If the sample contains Halide, it is subjected to
Beilstein test
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Beilstein test positive result
- indicated by a green flame.
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To observe the reactivity to SN1, it is made to react with
AgNO3.
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To observe the reactivity to SN2, it is made to react with
Nal Acetone
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The most common:Nucleophilic Substitution Reaction
replacement of the hydroxyl group of an alcohol
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The reaction may occur by one of two mechanisms designated
SN1 or SN2
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replacement of the hydroxyl group of an alcohol
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- kinetically a first-order reaction
SN1
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- takes place only on tertiary substrates and only under neutral or acidic conditions in a hydroxylic solvent such as water or alcohol.
SN1
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- reactions are unimolecular because the rate of reaction depends only on the concentration of one substance.
SN1
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kinetically second-order reaction
SN2
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- tert-butyl chloride is the fastest which means that the more stable the carbocation intermediate is, the faster it reacts through SN1.
SN1 Rxn
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Study Set Content:
Cyclohexene, benzene, toluene odor
FLASHCARD
A class of compounds where a halogen ato...
FLASHCARD
CHCl3
FLASHCARD
CF2Cl2
FLASHCARD
Halothane: anesthetic)
FLASHCARD
alkyl group attached to one carbon. E.g....
FLASHCARD
alkyl group attached to two carbon. E.g....
FLASHCARD
alkyl group attached to three carbon. E....
FLASHCARD
To know If the sample contains Halide, i...
FLASHCARD
Beilstein test positive result
FLASHCARD
To observe the reactivity to SN1, it is...
FLASHCARD
To observe the reactivity to SN2, it is...
FLASHCARD
The most common:Nucleophilic Substitutio...
FLASHCARD
The reaction may occur by one of two mec...
FLASHCARD
Item 95
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kinetically a first-order reaction
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takes place only on tertiary substrates...
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reactions are unimolecular because the r...
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kinetically second-order reaction
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tert-butyl chloride is the fastest which...
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