Study Set Content:
Reaction with an organo magnesium reagent to yield an alcohol
GRIGNARD REACTION
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Conversion of Acids into Acid Chlorides
- Treatment with thionyl chloride
- Acid is converted to chlorosulfite
- Chlorosulfite reacts with a chloride ion
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Reaction with alcohol where –OH is substituted to –OR
Conversion of Acids into Esters
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- heating of carboxylic acid with an acid catalyst in an alcohol solvent
Fischer esterification method
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Conversion of Acids into Amides
- treat with
dicyclohexylcarbodiimide (DCC)
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Conversion of Acids into Alcohols
- Reduction by
- lithium aluminum hydride
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- Most reactive of the derivatives specifically ACID CHLORIDE
Acid Halides and their Reactions
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ALCOHOLYSIS
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AMINOLYSIS
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REDUCTION
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HYDROLYSIS
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ACID DERIVATIVE
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GRIGNARD REACTION
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Halogen can be replaced by: -OH
acid
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-OR
ester
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-NH2
amide
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Reduced by LiAIH4
primary alcohol
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React with Grignard
tertiary alcohol
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- acid chlorides react with water to yield carboxylic acids v
Hydrolysis reactions
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Acid chloride + alcohol →
ester
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Study Set Content:
Reaction with an organo magnesium reagen...
FLASHCARD
Conversion of Acids into Acid Chlorides
FLASHCARD
Reaction with alcohol where –OH is subst...
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heating of carboxylic acid with an acid...
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Conversion of Acids into Amides
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Conversion of Acids into Alcohols
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Most reactive of the derivatives specifi...
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Item 168
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Item 169
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Item 170
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Item 171
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Item 172
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Item 173
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Halogen can be replaced by: -OH
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-OR
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-NH2
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Reduced by LiAIH4
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React with Grignard
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acid chlorides react with water to yield...
FLASHCARD
Acid chloride + alcohol →
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